Regensburg 2000 – scientific programme
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O: Oberflächenphysik
O 11: Postersession (Eröffnung)
O 11.124: Poster
Monday, March 27, 2000, 19:00–22:00, Bereich C
X-Ray Photoelectron study of a Cyclic Hexanuclear Cluster Entrapping an Alkaline Ion — •Sorin Gheorghe Chiuzbăian1, Manfred Neumann1, Bernd Schneider1, Oliver Waldmann2, I. Bernt3, and R.W. Saalfrank3 — 1Universität Osnabrück, Fachbereich Physik, D-49069 Osnabrück, Deutschland — 2Physikalisches Institut III, Universität Erlangen-Nürnberg, D-91058 Erlangen, Deutschland — 3Institut für Organische Chemie, Universität Erlangen-Nürnberg, D-91058 Erlangen, Deutschland
We report the first X-ray photoelectron study of a ferric-wheel. The sample investigated was a cyclic hexanuclear Fe(III) cluster entrapping an alkaline ion [Li ⊂ Fe6L6]Cl · 6CHCl3, L=N(CH2CH2O)3. The Fe 3s and 2p core level line spectra show clear features which were attributed to a ligand-metal charge transfer. Magnetic moments were also deduced from susceptibility measurements and compared with the size of the magnetic exchange splitting of the Fe 3s line, which is proportional to the local magnetic moment of the Fe ion.