Regensburg 2000 – wissenschaftliches Programm
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O: Oberflächenphysik
O 11: Postersession (Eröffnung)
O 11.23: Poster
Montag, 27. März 2000, 19:00–22:00, Bereich C
Two stoichiometric phases of the Mo:Se system grown on a MoS2 substrate by van der Waals epitaxy — •Thorsten Böker, Ralf Severin, Torsten Stemmler, Christoph Janowitz, and Recardo Manzke — Institut f. Physik; Humboldt-Universität zu Berlin; Invalidenstraße 110; 10115 Berlin
Van der Waals epitaxy (vdWe) is a powerfull tool to produce high quality thin films of low-dimensional materials. In the present study high-purity Mo and Se was evaporated in a new vdWe system by an electron beam evaporator and a Knudsen type effusion cell, respectively. The deposited film on a MoS2 substrate was investigated by low energy electron diffraction (LEED), Auger electron spectroscopy (AES), and angular-resolved photoelectron spectroscopy (ARPES). As a result two different stoichiometric phases were identified by AES for different growth parameters. These are MoSe2 and Mo6Se8, respectively. Their crystal structure was checked by LEED and the MoSe2 film showed a planar hexagonal pattern confirming a layer-by-layer growth mode as typically apparent in vdWe. In contrast the Mo6Se8 phase reveals a more wagon-wheel like LEED pattern which is attributed to a facetted surface. ARPES studies on such samples showed a more angle-integrated density of states instead of a dispersive valence-band structure observed for the MoSe2 phase.