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Berlin 2001 – scientific programme

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MO: Molekülphysik

MO 9: Photoionisation I (joint session A and MO)

MO 9.3: Talk

Thursday, April 5, 2001, 16:15–16:30, H1012

3p multiplet structure of Ti studied by photoelectron spectroscopy — •Kai Godehusen1, Sandra Brünken1, Birgit Kanngießer1, Peter Zimmermann1, and Michael Martins21Institut für Atomare und Analytische Physik, Technische Universität Berlin, Hardenbergstr. 36, D-10623 Berlin, Germany — 2Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin, Germany

The 3p photoemission of free Ti atoms has been studied using synchrotron radiation of the storage ring BESSY II in Berlin.

The 3p−1 electron spectrum of Ti is dominated by a strong 3p−3d interaction. It also shows extensively broadened low-spin states. This term dependent lifetime and the strong 3p−3d interaction can also be seen in the 3p spectra of other 3d transition metals. We have done Hartree-Fock calulations which support our findings.


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