Hamburg 2001 – wissenschaftliches Programm
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HL: Halbleiterphysik
HL 30: III-V Halbleiter II
HL 30.1: Vortrag
Donnerstag, 29. März 2001, 10:30–10:45, S16
Interband transitions in (GaP)1/(InP)m monolayer superlattice structures grown on (001) InP — •J. Šik1, M. Schubert1, T. Hofmann1, H. Schmidt1, G. Böhm1, and V. Gottschalch2 — 1Fakultät für Physik und Geowissenschaften, Inst. für Exp. Physik II, Universität Leipzig, Linnéstraße 5, 04103 Leipzig — 2Fakultät für Chemie und Mineralogie, Halbleiterchemie, Universität Leipzig, Linnéstraße 3, 04103 Leipzig
Spectroscopic ellipsometry (SE) and empirical pseudopotential calculations are used to study the optical properties of tensile strained short-period [001] (GaP)1/(InP)m monolayer (ML) superlattices (SL) for m = 5 - 55 and photon energies from 1 to 6 eV deposited on Si-doped (001) InP substrates by MOVPE. Structure, composition, strain and layer thicknesses are determined by HRTEM and HRXRD. Adachi’s critical-point composite model is employed for SE data analysis of the E0-, E0+Δ0-, E1- and E1+Δ1-type transitions of the SL’s. We report a much smaller blue shift of E0 compared to the respective strained random alloy GaxIn1−xP band gap, where x = 1/(1+m). The observed band-gap dependence on m is in good agreement with our empirical pseudopotential calculations. We estimate the maximum band-gap reduction ΔEg for CuAu-I-type ordered GaInP2 with [001] ordering direction. The E1- and (E1+Δ1)-CP dependences can be explained within the classical elasticity theory as sum of the effects of biaxial strain and alloying, as observed in recent piezo-optics experiments on InP [Rönnow et al., Phys. Rev. B 57, 4432 (1998)].