Regensburg 2002 – wissenschaftliches Programm
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CPP: Chemische Physik und Polymerphysik
CPP 3: Poster: Kristalline Polymere
CPP 3.1: Poster
Montag, 11. März 2002, 13:30–15:00, B
Studies on Elastic Polypropylene — •Andreas Boger1, Bernd Heise1, Othmar Marti1, Martin Pietralla1, Bernhard Rieger2, Carsten Troll2, Andreas Mayer3, and Martin Dommach3 — 1Univ. Ulm, Experimentelle Physik, Albert-Einstein-Allee 11, D-89069 Ulm — 2Univ. Ulm, Anorganische Chemie II, Albert-Einstein-Allee 11, D-89069 Ulm — 3Hasylab/DESY , Notkestrasse 85, D-22603, Hamburg,
Different elastic polypropylene were synthesized with new metallocene catalysts, activated by MAO (MethylAluminiumOxane) or borate. Depending on polymerization conditions a great variety of PPs with different stereoregularities and molecular weight distributions were polymerized with different physical structures and properties. The amount of stereo errors in the chains of these PPs influence the degree of crystallinity, resulting in either semi-crystalline flexible polymers or nearly amorphous highly elastic ones. Results obtained with Synchrotron and Guinier WAXS, DMA and SFM especially on elastic PP grades are presented. Stress strain measurements on highly elastic samples, such as the totally x-ray-amorphous ones, show the great potential of these novel PPs as a thermoplastic rubber material with high recovery and small hysteresis. These PPs also show pronounced strain induced crystallization accordance with well known conventional rubber.