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CPP: Chemische Physik und Polymerphysik

CPP 4: Poster: Dynamik in polymeren Systemen

CPP 4.7: Poster

Montag, 11. März 2002, 13:30–15:00, B

Dielectric spectroscopy of plasma copolymers of the system allyl alcohol/alkene — •Andreas Fritz, Andreas Schoenhals, Renate Mix, Gerhard Kuehn, and Joerg F. Friedrich — Bundesanstalt fuer Materialforschung und -pruefung, Unter den Eichen 87, 12205 Berlin, Germany

Polymers synthesized with plasma techniques are very interesting materials for electronic, optic, and bio compatible applications. Thin films of plasma polymers shows a good adhesion to metals, glass, or other polymers. But the supramolecular structure, the durability, and the chemical and mechanical behavior of these polymers is poorly understood. Therefore dielectric investigations are carried out to study the dynamic behavior of the plasma polymers. As polymer system allyl alcohol/alkene is chosen to get polymers with a defined concentration of hydroxyl groups. The dielectric investigations shows several relaxation processes and a dependency of the dielectric parameters from the ratio of allyl alcohol in the polymer is observed. This results indicated that the alkene monomers were assembled continuous into the polymer matrix.