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Berlin 2005 – scientific programme

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CPP: Chemische Physik und Polymerphysik

CPP 30: POSTER: Chemical physics

CPP 30.55: Poster

Tuesday, March 8, 2005, 16:30–18:30, Poster TU D

Negatively Charged Water Dispersible Prussian Blue Nanoclusters and Decoration of Single Polycation Chains and Carbon Nanotubes — •Ganna Gorodyska1, Vera Bocharova1, Anton Kiriy1, Paul Simon2, Manfred Stamm1, Xudong Lou3, Francois Stoffelbach3, Christophe Detrembleur3, and Robert Jérôme31Leibniz-Instituts für Polymerforschung Dresden, Hohe Straße 6, 01069 Dresden, Germany — 2Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Str. 40, 01187 Dresden, Germany — 3Center for Education and Research on Macromolecules (CERM), University of Liege, Sart-Tilman, B6, 4000 Liege, Belgium

A simple method is reported in this work for the preparation of charge-stabilized Prussian Blue nanocrystals of readily adjustable size. They have been purified by addition of non-solvents and redispersed in water without aggregation. PB nanocrystals have been electrostatically arranged along single polycation chains adsorbed onto flat surfaces or along carbon nanotubes precoated by a polycation. In the latter case, carbon nanotube-polyelectrolyte-Prussian Blue hybrids are formed, that might be useful materials for the manufacture of electrooptical devices or mechanically robust ion-sieving membranes.

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