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MO: Molekülphysik

MO 44: Novel Spectroscopies

MO 44.4: Vortrag

Dienstag, 8. März 2005, 17:15–17:30, HU 2097

Line Shapes in Time-of-Flight Mass Spectrometry: Application of a Genetic Algorithm — •Christof Maul — Institut für Physikalische und Theoretische Chemie, TU Braunschweig, Hans-Sommer-Str. 10, 38106 Braunschweig

A data analysis method is presented which is based on the application of a genetic algorithm to a forward convolution procedure which finds the best three-dimensional product momentum distribution from one-dimensional experimental data as typically obtained in reaction dynamics experiments utilising laser induced fluorescence or resonance enhanced multi-photon ionisation combined with time-of-flight measurements. The high performance of the method is demonstrated for a complex product distribution exhibiting a velocity dependent anisotropy behaviour.