Dresden 2006 – scientific programme
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CPP: Chemische Physik und Polymerphysik
CPP 27: POSTER Polymer Physics and Materials
CPP 27.28: Poster
Thursday, March 30, 2006, 17:00–19:00, P2
Substrate-Consuming Metal-Organic Layers (SCMOLs) from Thiol Derivatives - a combined SAXS/SEM Study. — •Birgit Riedel1, Matthias Barczewski1,2, Jochen Geerk3, Thomas Schimmel1,2, and Stefan Walheim1 — 1Institute for Nanotechnology, Forschungszentrum Karlsruhe, 76021 Karlsruhe (Germany) — 2Institute of Applied Physics, University of Karlsruhe, 76131 Karlsruhe (Germany) — 3Institute for Solid-State Physics, Forschungszentrum Karlsruhe, 76021 Karlsruhe (Germany)
Substrate-Consuming Metal-Organic Layers (SCMOLs) were prepared using a variety of thiol molecules. This new type of metal-organic dielectric films grow at room temperature from solution at the interface of the metal substrate and the newly formed metal-organic film. The resulting morphological characteristics of the various compounds were investigated by Small Angle X-Ray Scattering (SAXS) and Scanning Electron Microscopy (SEM). A strong correlation of the structural data and the molecular architecture could be observed and will be discussed. First results on the optical properties of these solid transparent films - with a thickness pre-selectable from a few nanometer up to 1 micrometer - will be presented.