Dresden 2006 – scientific programme
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DF: Dielektrische Festkörper
DF 2: Dielectric and Ferroelectric Thin Films and Nanostructures I
DF 2.1: Invited Talk
Monday, March 27, 2006, 14:30–15:10, M{\"U}L Elch
Size effects in ferroelectric nanostructures — •Andreas Rüdiger — Center of Nanoelectronic Systems for Information Technology, Institute of Solid State Research, Research Center Jülich, 52425 Jülich, Germany
Ferroelectrics are among the most advanced candidates for non-volatile memory applications. They are also widely used in pyroelectric sensors and piezoelectric actuators. As current integration techniques are driving the dimensions towards 10nm lateral extension and only a few unit cells height, the analogy to ferromagnetism raises the question if a lower size limit also exists for ferroelectrics. Earlier studies on free particles neglected electromechanical constraints imposed by conductive substrates and rather determined a pyroelectric limit (i.e. the size-driven transition into a centrosymmetric phase). Our results of piezoelectric force microscopy on e.g. ferroelectric BaTiO3 nanoislands indicate structural and functional integrity well below the critical volume of free particles. So far, there is no evidence of a size limit in ferroelectric nanoparticles on conducting substrates. We highlight the impact of the aforementioned electromechanical boundary conditions on ferroelectricity and discuss composition and time-scale as possible origins of a critical size below 10 nm.