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Berlin 2008 – wissenschaftliches Programm

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TT: Fachverband Tiefe Temperaturen

TT 36: Superconductivity: Properties, Electronic Structure, Order Parameter

TT 36.6: Vortrag

Freitag, 29. Februar 2008, 11:45–12:00, H 0104

Superconductivity in the new filled skutterudites MPt4Ge12 (M = La, Pr, Sr, Ba) — •Walter Schnelle, Roman Gumeniuk, Helge Rosner, Michael Nicklas, Andreas Leithe-Jasper, and Yuri Grin — Max-Planck-Institut für Chemische Physik fester Stoffe, Dresden, Germany

New germanium-platinum compounds with the filled-skutterudite crystal structure were synthesized [1]. The crystal structure and composition were investigated by X-ray diffraction and microprobe analysis. Magnetic susceptibility, specific heat, and electrical resistivity measurements evidence superconductivity in LaPt4Ge12 and PrPt4Ge12 below 8.3 K. The parameters of the normal and superconducting states were established. Strong coupling and a crystal electric field singlet groundstate is found for the Pr compound. Electronic structure calculations show a large density of states at the Fermi level [1]. Similar behavior albeit with lower Tc was observed for SrPt4Ge12 and BaPt4Ge12 [1,2].

[1] R. Gumeniuk et al. Phys. Rev. Lett. submitted. ArXiV 0710.1413v1.

[2] R. Gumeniuk et al. Poster, this conference.

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