Dresden 2009 – scientific programme

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 10: Polymer Physics I

CPP 10.6: Talk

Monday, March 23, 2009, 19:15–19:30, ZEU 114

Interfacial Polarization and Field Induced Orientation in Self Assembled Nanostructured Soft Ion Conductors — •Peter Kohn, Klaus Schröter, and Thomas Thurn-Albrecht — Institut für Physik, Martin-Luther-Universität Halle-Wittenberg

We report about the effects of interfacial polarization in and upon a self assembled nanostructured ion conductor, consisting of an ordered, lamellar block copolymer with a Lithium salt dissolved selectively in one component. Impedance spectroscopy in combination with frequency dependent orientation experiments enable a quantitative analysis of ionic polarization and a direct demonstration of its aligning effect on the interfaces. The transition time from the fast dielectric to the slow ionic interfacial polarization is much longer than expected from classical Maxwell-Wagner-Sillars theory and attributed to the formation of diffuse double layers at the internal interfaces. The much stronger orientation effect of ionic as compared to dielectric polarization offers a new route to align microdomains and therewith the ion conducting paths of the polymer.