Dresden 2009 – scientific programme
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CPP: Fachverband Chemische Physik und Polymerphysik
CPP 25: Diffusion and Dynamics
CPP 25.1: Talk
Wednesday, March 25, 2009, 15:30–15:45, ZEU 160
Hot Brownian Motion — •Daniel Rings1, Romy Radünz2, Frank Cichos2, and Klaus Kroy1 — 1ITP, Uni Leipzig, Germany — 2EXP1, Uni Leipzig, Germany
Brownian motion is abundant throughout the microscopic and mesoscopic world. Since Einstein’s seminal work, there is a good understanding of this process under conditions of thermal equilibrium. Brownian motion of particles in media with inhomogeneous temperature distributions poses several new questions. One way – already introduced by Maxwell – to cope with temperature gradients is to modify the boundary conditions at the particle’s surface and allow slip in order to account for effects of thermal gradients. This approach is purely phenomenological, however, and does not take into account the temperature-dependence of the solvent viscosity, which is pronounced in water and e. g. hence most relevant for biological systems.
Here, we present a simple theoretical model for a suspension of heated Brownian particles. We determine the Stokes’ flow around a spherical particle for radially varying viscosity and thus obtain effective quantities η, T. With these, we formulate a generalized Stokes-Einstein relation 6πη RD=kBT, which has been justified by a novel experimental technique called Photothermal Correlation Spectroscopy (PhoCS) presented by Romy Radünz also at this conference.