Hannover 2010 – wissenschaftliches Programm

Bereiche | Tage | Auswahl | Suche | Downloads | Hilfe

MO: Fachverband Molekülphysik

MO 16: Electronic Spectroscopy II

MO 16.2: Vortrag

Mittwoch, 10. März 2010, 17:00–17:15, F 102

IR spectroscopy applied to an electronically excited state of Bis(benzene)chromium — •Martin Weiler, Kristina Bartl, and Markus Gerhards — TU Kaiserslautern, Physikalische und Theoretische Chemie, Erwin-Schrödingerstr. 52, 67663 Kaiserslautern

IR/UV double and triple resonance spectroscopy in molecular beam experiments in combination with ab initio and DFT calculations yields information on structural changes subsequent to photoexcitation. We present the first application of the UV/IR/UV technique to a neutral organometallic compound. Information about the energy and the structure of the electronic ground state as well as the electronically excited Rydberg state (R4p_x,y) in bis(benzene)chromium (an example of a sandwich complex) can be discussed.