Hannover 2010 – scientific programme

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MO: Fachverband Molekülphysik

MO 16: Electronic Spectroscopy II

MO 16.8: Talk

Wednesday, March 10, 2010, 18:30–18:45, F 102

Photodissociation of the ethyl radical — •Kathrin Fischer, Patrick Hemberger, Michael Steinbauer, and Ingo Fischer — Institut für Physikalische und Theoretische Chemie, Universität Würzburg

Radicals and carbenes are species of great interest. They play an important role in combustion processes and in interstellar space. Those radicals and carbenes are generated by supersonic jet flash pyrolysis and the photodissociation dynamics is investigated by laser spectroscopy. Herin, we will focus on the ethyl radical, which was generated from ethyliodid and n-propylnitrit. For comparison we also investigated the deuterated species.Furthermore the rates for hydrogen loss were examined to archive information of the exited state.