Hannover 2010 – wissenschaftliches Programm

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UP: Fachverband Umweltphysik

UP 4: Remote Sensing

UP 4.6: Vortrag

Mittwoch, 10. März 2010, 15:30–15:45, M 11

Evidence for Iodine monoxide in the Antarctic snowpack from spectrosocopic Measurements — •Udo Frieß¹, Tim Deutschmann¹, Ben Gilfedder², Rolf Weller³, and Ulrich Platt¹ — ¹Institut für Umweltphysik, Universität Heidelberg — ²Institut für Umweltgeologie, TU-Braunschweig — ³Alfred Wegener Institut für Polar- und Meeresforschung, Bremerhaven

Recent ground-based and space borne observations suggest the presence of significant amounts of iodine monoxide in the boundary layer of Antarctica, which are expected to have an impact on the ozone budget and might contribute to the formation of new airborne particles. So far, the source of these iodine radicals has been unknown.

Here we present long-term measurements of iodine monoxide at the German Antarctic research station Neumayer, which indicate that the snowpack is the main source for iodine radicals. The measurements have been performed using multi-axis differential optical absorption spectroscopy (MAX-DOAS). Using a coupled atmosphere - snowpack radiative transfer model, the comparison of the signals observed from scattered skylight and from light reflected by the snowpack yields several ppb of iodine monoxide in the upper layers of the sunlit snowpack throughout the year. Snow pit samples from Neumayer Station contain up to 700 ng/l of total iodine, representing a sufficient reservoir for these extraordinarily high IO concentrations.