Regensburg 2010 – wissenschaftliches Programm
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CPP: Fachverband Chemische Physik und Polymerphysik
CPP 17: Interfaces and Thin Films I
CPP 17.6: Vortrag
Dienstag, 23. März 2010, 11:15–11:30, H39
The Softer the Better: Fast Condensation on Soft Surfaces — Mordechai Sokuler1, 2, •Günter K. Auernhammer1, Marcel Roth1, Chuanjun Liu1, 2, Elmar Bonaccurso1, and Hans-Jürgen Butt1 — 1MPI Polymer Research, Mainz, Germany — 2Center of Smart Interfaces, TU Darmstadt, Germany
Condensation on soft elastic surfaces differs significantly from condensation on hard surfaces [1]. On polymeric substrates with varying cross-linking density, we investigate the nucleation and the growth of condensing water drops. Surface roughness and apparent contact angle are shown to be very similar on all surfaces. The surfaces differ in the elastic module and viscosity. With increasing softness of the substrates, we find (1) increasing nucleation density, (2) longer relaxation times for drop shape equilibration after merging of two drops, and (3) prevention of merging on very soft surfaces. These effects lead to higher surface coverage and overall condensed volume on soft surfaces.
[1] M. Sokuler et al. Langmuir (2009), DOI: 10.1021/la903996j