Regensburg 2010 – wissenschaftliches Programm

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DS: Fachverband Dünne Schichten

DS 10: Plasmonics and Nanophotonics I (Joint Session DS/O/HL)

DS 10.1: Vortrag

Dienstag, 23. März 2010, 10:30–10:45, H2

Electrochemically tunable photonic metamaterial — •Lihua Shao, Stefan Linden, Matthias Ruther, Jörg Weißmüller, and Martin Wegener — Institut für Nanotechnologie and DFG-Center for Functional Nanostructures (CFN), Karlsruhe Institute of Technology (KIT), Karlsruhe, Germany

We report experiments to combine two approaches for designing functional nanomaterials. Photonic metamaterials provide a strategy for obtaining unconventional optical response - in the extreme, negative refractive indices - by lithographically structured elements like arrays of split-ring resonators (SRR). Nanomaterials with tunable electronic structure exploit large specific surface area of metal nanostructures to tune the surface properties through the controlled space-charge regions for tuning macroscopic properties. The combination is a photonic metamaterial in which the space-charge at the surface of SRR is controlled via an applied potential, leading to a tunable optical resonance. We report first results support this concept. SRR structures with resonance frequencies in the near infrared are immersed into aqueous electrolytes as working electrode in an electrochemical experiment. Varying the electrode potential, E, induces a space-charge layer at the metal surface as part of the electrochemical double-layer. We find the resonance frequencies vary linearly, reversibly, and reproducibly with E, with a blue shift for negative potential. A tentative explanation is based on the effective thickening of the SRR by the excess electrons, which changes the SRR aspect ratio. The observation of larger frequency shift for thinner SRR's is compatible with this scenario.