Regensburg 2010 – wissenschaftliches Programm

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DS: Fachverband Dünne Schichten

DS 15: [HL] Organic Semiconductors: Transistors and OLEDs (Joint Session DS/CPP/HL/O)

DS 15.2: Vortrag

Dienstag, 23. März 2010, 09:45–10:00, H15

Electrolyte-gated organic thin film transistors — •Felix Buth¹, Marin Steenackers², Deepu Kumar¹, Martin Stutzmann¹, and Jose Antonio Garrido¹ — ¹Walter Schottky Institut, Technische Universität München, Am Coulombwall 3, 85748 Garching, Germany — ²Institute for Advanced Study, Technische Universität München, Arcisstr. 21, 80333 München, Germany

Organic semiconductors are today widely used as the active material in several applications based on thin film transistors. For most of these devices large operational voltages are required. One approach to reduce the gate voltage is increasing the capacitance of the gate dielectric. Several materials, including high-k dielectrics, ultra-thin cross-linked polymers or polyelectrolytes have been tested for this purpose. Among those, polyelectrolytes offer extraordinarily high capacitances with a relatively low technology cost. The high capacitance results from the electrical double layer formed at the polyelectrolyte/semiconductor interface, opening the possibility of using organic thin film transistors for biological and chemical sensors, in which in-electrolyte operation is required. Since, however, water stable organic semiconductors are generally deposited by evaporation in UHV, the surface of the polyelectrolyte needs to be smooth to enable the growth of high quality films. In this contribution the properties of different polyelectrolyte dielectrics are investigated. We show how polyelectrolytes can be directly prepared on conductive substrates, resulting in homogeneous films with high interfacial capacitances. Furthermore, we show the preparation of high quality pentacene thin films onto the polyelectrolyte films.