Dresden 2011 – wissenschaftliches Programm

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 5: Organic Semiconductors I: Solar Cells A (jointly with HL, DS)

CPP 5.7: Vortrag

Montag, 14. März 2011, 16:00–16:15, ZEU 222

The effect of energetic disorder on open-circuit voltage in organic photovoltaics — •James C Blakesley, Ilja Lange, and Dieter Neher — University of Potsdam, Germany

Open-circuit voltage (VOC) is one of the most important figures of merit describing the quality of organic photovoltaics (OPVs). Usually it is assumed that VOC depends on the energy difference between the highest occupied molecular orbital (HOMO) of the donor and the lowest unoccupied molecular orbital (LUMO) of the acceptor, but large deviations from this trend are often found. In reality, there is a distribution of energy levels within the components, and this should also be taken into account.

We simulate bulk heterojunction OPVs using a simulation that includes the effects of energetic disorder [1].We find that VOC depends on: 1) the nominal donor-HOMO to acceptor-LUMO energy gap; 2) the charge-carrier generation and recombination rates; 3) the electrodes; and 4) the amount of energetic disorder. While the first three of these points have been much discussed previously, the effect of the fourth has not been conclusively demonstrated. An increase in the amount of energetic disorder leads to a reduction in the VOC due to relaxation of the carriers into the lowest lying energy levels. We find an analytical expression that predicts well the modelled VOC, and suggest the use of an effective donor-acceptor energy gap that takes energetic disorder into account. Measurements of Fermi-level pinning might be useful for determining this effective energy gap. [1] J. C. Blakesley and N. C. Greenham, J. Appl. Phys. 106, 034507 (2009)