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DS: Fachverband Dünne Schichten

DS 20: Application of Thin Films

DS 20.2: Vortrag

Dienstag, 15. März 2011, 10:30–10:45, GER 38

The influence of the crystallinity of TiO2 on the resistive switching behavior of memristor devices — •Hannes Mähne1, Stefan Slesazeck1, Stefan Jakschik1, and Thomas Mikolajick1,21NaMLab gGmbH, Dresden, Germany — 2Institut für Halbleiter und Mikrosystemtechnik, TU Dresden, Germany

Since 1970, Chua postulates the existing of a memristor and HP found the first device in 2008, a lot of research has been done. Several research groups using successfully titanium oxide without detailed understanding of the switching mechanism. The following work fill a gap of information and create a link between the crystalline structure of TiO2 and its switching parameters. In this work used structure consists of Si substrate with thermally grown SiO2 and deposited Ti as adhesion layer before Pt was sputtered as an inert bottom electrode. After deposition of TiO2, by RF sputtering from a TiO2 target with additional 2 sccm O2, the material is in an amorphous phase. To get different phases the samples are annealed in a RTP oven at 500C and 700C in Ar atmosphere and with O2. The top electrode material was evaporated aluminum. To create a temperature stable bottom electrode, several bottom layer stacks are tested and results in a thick Pt layer on a preoxidized Ti adhesion layer. Otherwise the bottom electrode becomes damaged. A reason for this behavior is that thin Pt becomes crystalline and holes are created. Next to this, temperatures above 700C causes cracks in the TiO2 films. The change in crystallinity results in a change from a oxygen migration like switching in amorphous to a filament like switching behavior in the crystalline samples.

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DPG-Physik > DPG-Verhandlungen > 2011 > Dresden