Dresden 2011 – scientific programme
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KR: Fachgruppe Kristallographie
KR 5: Poster Multiferroics (Joint Session of MA, DF, DS, KR, TT)
KR 5.1: Poster
Tuesday, March 15, 2011, 10:45–13:00, P2
XPS investigation of a tetranuclear nickel complex — •Daniel Taubitz1, Phalguni Chaudhuri2, Vitaly Pavlishchuk2, Karsten Kuepper3, and Manfred Neumann1 — 1Department of Physics, University of Osnabrück, Barbarastrasse 7, D-49069 Osnabrück, Germany — 2Max-Planck-Institut für Strahlenchemie, Stiftstrasse 34-36, D-45470 Mülheim an der Ruhr, Germany — 3Department of Solid State Physics, University of Ulm, Albert-Einstein-Allee 11, D-89069 Ulm, Germany
Organic transition metal complexes could be potentially useful for the development of new materials in the field of molecular magnetism. In this work we report on the investigation of a tetranuclear [Ni4 (HL)3]2+ compound which was characterised by X-ray photoelectron spectroscopy. A comparison with similar nickel complexes will be discussed. During the X-ray spectroscopic investigation some radiation induced damage was observed and studied in more detail. It turned out that the main damage was a decomposition of the ClO4− anions.