Berlin 2012 – scientific programme
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DS: Fachverband Dünne Schichten
DS 19: Poster I: Multiferroics (jointly with MA, DF, KR, TT), Spins in organic materials (jointly with MA), FePt Nanoparticles (jointly with MA, MM)
DS 19.3: Poster
Tuesday, March 27, 2012, 12:15–15:15, Poster A
EPR study of hyperfine interactions in Cu(II)- bis(oxamato) complexes — •A. Aliabadi1, A. Petr1, M. A. Abdulmalic2, T. Rüffer2, V. Kataev1, and B. Büchner1 — 1IFW Dresden, Dresden, Germany — 2Institute of Chemistry, Chemnitz University of Technology, Chemnitz, Germany
The hyperfine (HF) coupling of two Cu(II)-bis(oxamato) complexes containing four nitrogen ligands has been investigated using EPR spectroscopy at 10 GHz. The EPR spectra were modeled in order to determine the g-factor and the HF coupling values. First, measurements were performed on a liquid solution at room temperature to obtain isotropic g-factor and HF coupling constants for Cu and N. From the EPR measurements on powder samples we were able to extract the g-tensor and the Cu HF coupling tensor. In addition, the angular dependence of the EPR spectra was studied by rotation of a single crystal in three mutually perpendicular planes. From that the Cu HF coupling tensor was further refined and the N HF coupling tensor was determined. The results indicate that the difference between the determined parameters for two complexes is not significant. However, these parameters are smaller compared to a previous study of Cu(II)-bis(oxamato) complex containing two nitrogen ligands [1]. The results of this work should enable the determination of the spin density distribution between the central metal ion and the ligands in the studied molecules.
[1] B. Bräuer, T. Rüffer, R. Kirmse, J. Griebel, F. Weigend, G. Salvan, Polyhedron. 26 (2007) 1773.