Berlin 2012 – scientific programme
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DS: Fachverband Dünne Schichten
DS 19: Poster I: Multiferroics (jointly with MA, DF, KR, TT), Spins in organic materials (jointly with MA), FePt Nanoparticles (jointly with MA, MM)
DS 19.4: Poster
Tuesday, March 27, 2012, 12:15–15:15, Poster A
Magnetic properties of a mixed valence Ni(II)-Ni(III)-complex as probed by the ESR spectroscopy and static magnetization measurements — •Jaena Park1,3, Yulia Krupskaya1, Vladislav Kataev1, Bernd Büchner1, Frederik Schleife2, Berthold Kersting2, and Rüdiger Klingeler3 — 1Leibniz Institute for Solid State and Materials Research IFW Dresden, Dresden, Germany — 2Institute of Inorganic Chemistry, University of Leipzig, Leipzig, Germany — 3Kirchhoff Institute for Physics, University of Heidelberg, Heidelberg, Germany
We investigated magnetic properties of a mixed valence Ni(II)-Ni(III)-complex by means of high-field electron spin resonance spectroscopy and static magnetization measurements. The metal core of the complex contains one Ni2+ ion (S=1) and one Ni3+ ion (S=1/2) coupled by three sulphur bridges. The magnetic field dependence of the magnetization at low temperatures and the temperature dependence of the static magnetic susceptibility reveal a ferromagnetic coupling between the Ni-spins. The high-field frequency tunable electron spin resonance measurements enable determination of the g-factor and magnetic anisotropy values for the studied complex. In addition, we compare the magnetic properties of the Ni(II)-N(III)-complex with those of the similar structure Ni(II)-N(II)-complex having both Ni ions in the 2+ oxidation state.