Berlin 2012 – wissenschaftliches Programm

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DS: Fachverband Dünne Schichten

DS 8: Thin film photovoltaics: oxides and nanostructures

DS 8.5: Vortrag

Montag, 26. März 2012, 17:30–17:45, H 2032

Tantalum incorporation in TiO2 based transparent conductive thin films — •Marcel Neubert, Mykola Vinnichenko, Steffen Cornelius, and Andreas Kolitsch — HZDR

The growing number of applications of transparent electrodes in optoelectronic devices drives the need for novel cost-efficient transparent conductive materials. The epitaxial films of TiO2 doped with Nb or Ta show electrical resistivity values comparable to those of the best In2O3:Sn and ZnO:Al films. However, it is still challenging to achieve low electrical resistivity in polycrystalline TiO2-based films. In order to address this problem, we studied the films formed on glass substrates without heating by DC magnetron sputtering of reduced TiO2:Ta ceramic targets followed by vacuum annealing. It was crucial to use a plasma feedback system in order to enable a fine tuning of the oxygen supply into Ar and O2 gas mixture during the deposition. This approach yielded the 400 nm thick films with optical transmittance above 80%, electrical resistivity in the range of 10-3 *cm and free electron mobility of 8 cm*/Vs. The electrical activation of Ta dopant was above 60% that is substantially higher than that of Al in ZnO.