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Berlin 2012 – wissenschaftliches Programm

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DY: Fachverband Dynamik und Statistische Physik

DY 31: Phase Transitions and Critical Phenomena

DY 31.12: Vortrag

Freitag, 30. März 2012, 12:45–13:00, MA 004

Numerical study of polymer adsorption on a fractal substrateViktoria Blavatska1,2 and •Wolfhard Janke11Institut für Theoretische Physik, Universität Leipzig, Germany — 2Institute for Condensed Matter Physics, National Academy of Sciences of Ukraine, Lviv, Ukraine

We study the adsorption of flexible polymer macromolecules on a percolation cluster, formed by a regular two-dimensional disordered lattice at critical concentration pc of attractive sites. The percolation cluster is characterized by a fractal dimension dspc=91/49. The conformational properties of polymer chains grafted to such a fractal substrate are studied by means of the pruned-enriched Rosenbluth method (PERM). We find estimates for the surface crossover exponent governing the scaling of the adsorption energy in the vicinity of the transition point, φspc=0.425±0.009, and for the adsorption transition temperature, TApc=2.64±0.02. As expected, the adsorption is diminished when the fractal dimension of the substrate is smaller than that of a plain Euclidean surface. The universal size and shape characteristics of a typical spatial conformation which attains a polymer chain in the adsorbed state are analyzed as well.

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