Berlin 2012 – wissenschaftliches Programm
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HL: Fachverband Halbleiterphysik
HL 33: Ge/Si II
HL 33.1: Vortrag
Dienstag, 27. März 2012, 09:30–09:45, EW 015
Ion-beam mixing in crystalline and amorphous germanium isotope multilayers — •M. Radek1, H. Bracht1, R. Kube1, M. Posselt2, and B. Schmidt2 — 1WWU Münster — 2HZDR
Self-atom mixing induced by Gallium (Ga) implantation in crystalline and amorphous germanium (Ge) is investigated using an isotopic multilayer structure of alternating 73Ge and natGe layers grown by molecular beam epitaxy. The distribution of the implanted Ga atoms and ion-beam induced depth-dependent mixing was determined by means of the secondary ion mass spectroscopy (SIMS). The position and form of the implanted Ga peak is very similar in the amorphous and crystalline Ge and can be reproduced accurately by computer simulations based on binary collision approximation (BCA), whereas the ion-beam induced self-atom mixing strongly depends on the state of the Ge structure. The data from SIMS-measurements reveal a stronger mixing in the crystalline than in the amorphous Ge. Atomistic simulation based on BCA can reproduce the experimental data only if unphysically low displacement energies are assumed. The low displacement energies deduced within the BCA approach are confirmed by experiments with mixing induced by silicon implantation. The disparity observed in the ion-beam mixing efficiency of crystalline and amophous Ge indicates different dominant mixing mechanisms. We propose that self-atom mixing in crystalline Ge is mainly controlled by radiation enhanced diffusion during the early stage of mixing before the crystalline structure turns into an amorpous state, whereas in an already amoprhous state self-atom mixing is mediated by cooperative diffusion events.