Berlin 2012 – scientific programme

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KR: Fachgruppe Kristallographie

KR 2: Joint Session "Multiferroics I - Junctions and Thin Films / Magnetoelectric Coupling" (MA jointly with DF, DS, KR, TT), Organization: Manfred Fiebig (ETH Zürich)

KR 2.4: Talk

Monday, March 26, 2012, 10:30–10:45, EB 301

Thermally stimulated currents in BiFeO₃ — •Akash Bhatnagar, Ayan Roy Chaudhuri, Dietrich Hesse, and Marin Alexe — Max Planck Institute of Microstructure Physics, Weinberg 2, Halle(Saale), Germany

Bismuth ferrite(BiFeO₃)-BFO is a well known multiferroic material, with high ferroelectric Curie temperature (1103 K) and a saturated ferroelectric hysteresis with a remnant polarization of 100 C/cm². However, it has been found that pure BFO usually exhibits a high leakage current that could limit wide applications of this material. The thermally stimulated current (TSC) technique was used to get insights into the electronic origin of the leakage, which includes the study of energy levels that might be present in the band gap. These levels can act as trapping centers for charge carriers, thus affecting conductivity. Three systems of BFO, namely, single crystals, thin films and ceramics were studied. Measurements for ceramics and single crystals were performed in capacitor mode, whereas for thin films in-plane electrodes were made using a normal lift-off process. The effect of orientation of the electrodes with respect to domain patterns in thin films, have been investigated. Consequently, trap activation energies and density calculations were performed to fully characterize different levels. Photoconductive and photovoltaic properties were also investigated which corroborate the TSC data.