Berlin 2012 – wissenschaftliches Programm

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KR: Fachgruppe Kristallographie

KR 5: Poster I – including Multiferroics (MA with DF, DS, KR, TT)

KR 5.17: Poster

Dienstag, 27. März 2012, 12:15–15:15, Poster A

Synthesis and magnetic properties of cobalt ferrite nanoparticles — •Morad F. Etier¹, Vladimir V. Shvartsman¹, Frank Stromberg², Joachim Landers², Heiko Wende², Fábio G. Figueiras³, and Doru C. Lupascu¹ — ¹Institute for Materials Science, University of Duisburg-Essen, Essen, Germany — ²Faculty of physics and Center for Nanointegration (CeNIDE) Duisburg-Essen, University of Duisburg-Essen, Duisburg, Germany — ³Department of Physics, CICECO, University of Aveiro, Aveiro, Portugal

Cobalt ferrite is one of the most widely used materials in magnetic recording devices due to its high coercivity (about 5400 Oe), moderate magnetization (84 emu/g), and good chemical stability. Below Tc = 820 K cobalt ferrite is in a ferrimagnetic state. The magnetic properties of cobalt iron oxide nanoparticles mainly depend on the annealing temperature and particle size.

Nanoparticles of cobalt ferrite were successfully fabricated by the co-precipitation method. The crystal structure was confirmed by X-ray diffraction, the composition by energy dispersive spectroscopy, and phase changes by thermogravimetric differential thermal analysis. The particle morphology was analyzed by scanning electron microscopy. Magnetic properties were investigated by magnetometry and Mössbauer spectroscopy. Particle size is in the range of 24 to 44 nm. Both the particle size and agglomeration level are controlled by the amount of sodium hydroxide used. Dependence of remnant magnetization and coercive field on particle size is analyzed.