Berlin 2012 – wissenschaftliches Programm
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O: Fachverband Oberflächenphysik
O 5: Adsorption on semiconductors, oxides and insulators I
O 5.4: Vortrag
Montag, 26. März 2012, 11:15–11:30, MA 042
New mechanism for work-function tuning: ZnO surfaces modified by a strong organic electron acceptor — •Yong Xu1, Oliver T. Hofmann1, Patrick Rinke1, Matthias Scheffler1, Raphael Schlesinger2, Norbert Koch2, and Antje Vollmer3 — 1Fritz Haber Institute Berlin — 2Humboldt-Universität zu Berlin — 3Helmholtz-Zentrum Berlin
A key task for optimizing optoelectronic devices comprising hybrid inorganic/organic systems is to control the energy level alignment at interfaces. The use of interlayers provides a pathway to solve this challenge. To demonstrate the concept we investigated the polar surfaces of ZnO, modified by the prototypical organic electron acceptor 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ) theoretically and experimentally. DFT-PBE ΔSCF calculations of the O 1s surface core-level shifts combined with XPS measurements suggest that ZnO(000-1)/ZnO(0001) are H/OH covered. Depositing F4TCNQ on these surfaces considerably increases the work function that is shown to be insensitive to the doping level. F4TCNQ on ZnO(0001) exhibits an extraordinary high work function due to the appearance of upright adsorption. The PBE+vdW results are in line with the UPS data that shows work-function increases up to 1.4/2.8 eV on ZnO(000-1)/ZnO(0001). In contrast to F4TCNQ on metals, where pronounced bidirectional charge transfer occurs, the charge transfer to F4TCNQ is small, pinning the LUMO close to the Fermi level. The polarization of the system, caused by strong charge rearrangement within the adsorbate, is the main mechanism for the large work-function increase.