Hannover 2013 – scientific programme

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MO: Fachverband Molekülphysik

MO 14: Poster 1: Cluster, Femtosecond Spectroscopy

MO 14.3: Poster

Tuesday, March 19, 2013, 16:00–18:30, Empore Lichthof

Two-dimensional vibronic spectroscopy of molecular predissociation — •Julian Albert, Alexander Schubert, and Volker Engel — Institut für Physikalische und Theoretische Chemie, Universität Würzburg, Emil-Fischer-Str. 42, Am Hubland, 97074 Würzburg, Germany

We calculate two-dimensional (2D) spectra reflecting the time-dependent electronic predissociation of a diatomic molecule. The laser-excited electronic state is coupled non-adiabatically to a fragment channel, leading to the decay of the prepared quasi-bound states. This decay can be monitored by the three-pulse configuration employed in optical 2D-spectroscopy. It is shown that in this way it is possible to state-selectively characterize the time-dependent population of resonance states with different lifetimes. A model of the NaI molecule serves as a numerical example.