Regensburg 2013 – scientific programme

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 43: Organic Electronics and Photovoltaics V (joint session CPP/HL/O/DS)

CPP 43.4: Talk

Thursday, March 14, 2013, 16:00–16:15, H34

Electropolymerized polythiophenes as contact layers in organic solar cells — •Sidhant Bom and Veit Wagner — Jacobs University Bremen, Campus Ring 1, 28759 Bremen, Germany

Electropolymerized thiophene offers additional advantages to solution processable thiophenes because the doping concentration can be controlled with electrical parameters. The in-situ electrochemical doping provides a handle for the optimization of organic solar cells, either as a bulk polymer in the active layer or as an electron blocking layer. Here in this study, thiophenes are grown electrochemically with a standard three electrode system on Indium Tin Oxide (ITO) contacts. Characterization by UV-Vis measurements reflects the tunable final oxidation state of the thiophene layer. Thin layers are used in diode configuration using metal contacts like Au, Ag, Al and Cu. Static IV measurement allows the characterization of the contact according to Schottky model. Impedance measurements are used to determine the doping level of the layer. The doping level is found to be systematically depending on the applied negative bias during growth at the working ITO electrode with respect to the counter electrode. Applying a negative bias for a short interval at the end of the growth results in highly doped layers which are suitable for contact layers in solar cells.