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Regensburg 2013 – scientific programme

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HL: Fachverband Halbleiterphysik

HL 79: Focus Session: Frontiers of electronic structure theory VI (O, jointly with HL, TT)

HL 79.9: Talk

Thursday, March 14, 2013, 12:45–13:00, H36

Thermionic emission from metal surfaces: A first principles study — •Johannes Voss1, Sharon Chou1, Aleksandra Vojvodic1,2, Igor Bargatin3, Roger Thomas Howe1, and Frank Abild-Pedersen21Stanford University, USA — 2SLAC National Accelerator Laboratory, USA — 3University of Pennsylvania, USA

The ability to lower the temperatures required for sufficient electronic emission from hot cathodes would lead to more efficient thermionic energy converters and electron guns. Thermionic emission of electrons from metal surfaces is governed by the work function and tunneling probabilities. While the former can be extracted easily from ab initio band structure calculations, for the latter, scattering properties of the surface need to be taken into account.

Here, we present density functional theory calculations of thermionic emission currents based on a non-equilibrium Green’s function approach. We compare these results to experiments both for clean and coated metal surfaces. Based on an analysis of interactions in the coating layers, we suggest design pathways for new materials with higher emission current densities.

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