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O: Fachverband Oberflächenphysik

O 35: Poster Session I (Metal, semiconductor and oxide substrates: structure and adsorbates; Graphene)

O 35.16: Poster

Dienstag, 12. März 2013, 18:15–21:45, Poster B1

Self-assembled Monolayers of Paramagnetic Molecules on Gold revealed by Scanning Tunneling Microscopy — •christian salazar¹, danny baumann¹, ronny schlegel¹, torben hänke¹, jochen lach², berthold kersting², bernd büchner^{1, 3}, and christian hess¹ — ¹Institute for Solid State Research, IFW Dresden, Germany — ²Institute für Anorganische Chemie, Universität Leipzig, Germany — ³Department of Physics, TU Dresden, Germany

We have studied self-assembled monolayers of organic dinickel (II) complexes with an S=2 high paramagnetic state, anchored to a Au(111) surface via thiol groups using STM at room temperature. Our data clearly reveal the dense distribution of 2-4 nm sized objects on the Au surface, which evidences the growth of a closed molecular monolayer. The monolayers, however, do not show long-range order of the individual molecules.