Berlin 2014 – scientific programme
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MO: Fachverband Molekülphysik
MO 5: Posters 1: Electronic Spectroscopy, Photochemistry, Femtosecond Spectroscopy
MO 5.18: Poster
Monday, March 17, 2014, 16:30–18:30, Spree-Palais
Photophysics of Pyrophosphito-bridged diplatinum complexes — •Benedikt Burgard1, Florian Bäppler1, Patrick Singer1, Fabian Rupp1, Rolf Diller1, Christoph Riehn2, Yevgenyi Nosenko2, Dimitri Imanbaew2, and Sebastian Kruppa2 — 1Dept. of Physics, Univ. Kaiserslautern, 67663 Kaiserslautern, Germany — 2Dept. of Chemistry, Univ. Kaiserslautern, 67663 Kaiserslautern, Germany
The binuclear platinum(II) complex [Pt2(µ-P2O5H2)4]4−(PtPOP) exhibits interesting ultrafast photoinduced dynamics[1,2]. We employ fs transient absorption in the UV/Vis and mid-IR in solution and fs pump-probe photofragmentation (PF) of isolated anionic PtPOP species in gas phase, generated by electrospray ionization. Wavelength dependent PF studies provide information on electronic states and fragmentation behavior. Cooperative effects with respect to electronic and nuclear dynamics of M-PtPOP(-M) (M = Ag+, Tl+) species were studied. Wavepacket motion and transient IR spectra give information on structural dynamics. Solution experiments are compared to those in gas phase evaluating the influence of the solvent on energy relaxation processes (IC, ISC).
[1] R. M. van der Veen, A. Cannizzo, F. van Mourik, A. Vlček Jr., M. Chergui, JACS, 133, 305 (2011).
[2] M. Christensen, K. Haldrup, K. Bechgaard, R. Feidenhans’l, Q. Kong, M. Cammarata, M. Lo Russo, M. Wulff, N. Harrit, M. M. Nielsen, JACS, 131, 502-508 (2009).