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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 53: Organic Electronics and Photovoltaics B (original: DS, joined by CPP, HL, O)

CPP 53.3: Vortrag

Donnerstag, 3. April 2014, 18:15–18:30, CHE 91

Asymmetry of mixing length scales and kinetics of phase-separation in co-evaporated donor-acceptor organic thin film blends — •Rupak Banerjee, Christopher Lorch, Alexander Gerlach, Jiří Novák, Christian Frank, Johannes Dieterle, and Frank Schreiber — Institut für Angewandte Physik, Universität Tübingen, Auf der Morgenstelle 10, 72076 Tübingen, Germany

Small molecular organic semiconductors have found widespread usage in organic photovoltaics (OPV) due to their attractive optical, structural and electronic properties [1]. One of the many ways to tune the efficiency of an OPV is by mixing donor (D) and acceptor (A) materials [1] since the efficiency depends on the interplay of the diffusion lengths of the excitons generated by the absorption of light and the structural length scales of the D:A mixture. Controlling the structural length scales in D:A mixtures is thus of paramount importance [2]. We discuss in situ and real-time x-ray scattering studies on the structure of mixed D:A films as a function of mixing ratio which reveal the kinetics and thickness dependence of phase separation and in particular the asymmetry between top and bottom interfaces [3]. We further discuss the influence of interrupted growth on the phase-separation kinetics of such systems.

[1] W. Brütting and C. Adachi, Physics of Organic Semiconductors, Wiley-VCH, Weinheim (2012).

[2] A. Opitz et al., IEEE J. Sel. Top. Quant. 16, 1707 (2010).

[3] R. Banerjee, J. Novák, C. Frank, C. Lorch, A. Hinderhofer, A. Gerlach, and F. Schreiber, Phys. Rev. Lett. 110, 185506 (2013).