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Dresden 2014 – wissenschaftliches Programm

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TT: Fachverband Tiefe Temperaturen

TT 101: Transport - Poster Session

TT 101.17: Poster

Donnerstag, 3. April 2014, 15:00–19:00, P2

Electronic structure of photosensitive molecular switches: A first-principle investigation — •Lokamani L1, Daijiro Nozaki1, Arezoo Dianat1, Tahereh Ghane1, Rafael Gutierrez1, and Gianaurelio Cuniberti1,2,31Institute for Materials Sciences and Max Bergmann Center of Biomaterials, TU Dresden, 01062 Dresden Germany — 2Dresden Center for Computational Materials Science, TU Dresden, Germany — 3Center for Advancing Electronics Dresden, TU Dresden, Germany

The investigation of networks of nano-particles interconnected with functional molecular components is an active research field. Some potential applications include the realization of elementary computing units, able to act as memory nano-devices. However, to achieve this goal a detailed understanding of the electronic, structural, and electrical transport properties of potentially relevant molecular building blocks is mandatory. Here, we study such properties at the level of single molecules, for merocyanine derivatives, a photosensitive organic complex. In particular, we analyse the interplay between molecular conformation and corresponding modifications in the electrical response. First steps towards the inclusion of structural fluctuations via molecular dynamics simulations and its impact on the charge transport are also discussed.

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