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TT: Fachverband Tiefe Temperaturen

TT 3: Magnetic/Organic Interfaces and Molecular Magnetism (organized by MA; with CPP, DS, HL, O, TT)

TT 3.5: Hauptvortrag

Montag, 31. März 2014, 11:45–12:15, HSZ 02

Linking magnetic molecules to themselves, to others and to surfaces — •Richard Winpenny — University of Manchester, United Kingdom

We are learning how to link together polymetallic compounds to give complex structures [1]. During this presentation recent work will be discussed in two distinct approaches. Firstly, we will describe recent work creating new hybrid inorganic-organic rotaxanes [2] and in the second approach we will discuss functionalising polymetallic rings so that they can act as ligands for other metal complexes and surfaces [3,4]. We will also describe the use of pulsed EPR spectroscopy to measure weak interactions between these molecular magnets.

1.G. A. Timco, T. B. Faust, F. Tuna and R. E. P. Winpenny, Chem. Soc. Rev., 2011, 40, 3067-3075. 2.C.- F. Lee, D. A. Leigh, R. G. Pritchard, D. Schultz, S. J. Teat, G. A. Timco and R. E. P. Winpenny, Nature, 2009, 458, 314-318. 3.G. A. Timco, S. Carretta, F. Troiani, F. Tuna, R. G. Pritchard, E. J. L. McInnes, A. Ghirri, A. Candini, P. Santini, G. Amoretti, M. Affronte and R. E. P. Winpenny, Nature Nanotechnology, 2009, 4, 173-178. 4 G. F. S. Whitehead, F. Moro, G. A. Timco, W. Wernsdorfer, S. J. Teat and R. E. P. Winpenny, Angew. Chem. Int. Ed., 2013, 52, 9932-9935.