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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 10: On-surface Polymerization

CPP 10.2: Hauptvortrag

Montag, 16. März 2015, 15:30–16:00, H 0105

Selective C-H Activation and C-C coupling on Metal Surfaces — •Lifeng Chi — Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou 215123, P. R. China — Physikalisches Institut, Universität Münster, Wilhelm-Klemm-Strasse 10, 48149 Münster, Germany

Selective C-H bond activation is one of the most interesting and challenging topics in chemical synthesis. Recently, the development of the *on surface chemistry* provides an alternative strategy for the C-H activations. In this talk an overview for C-H activation and the following C-C coupling on metal surfaces will be given, together with detailed report on alkane homo-coupling and aryl-aryl coupling via the C-H activation by introducing OH group in phenyl rings. The influence of metal surfaces on reaction activation and selectivity will be discussed.