Berlin 2015 – wissenschaftliches Programm

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 45: P10: Colloids and Complex Liquids

CPP 45.10: Poster

Mittwoch, 18. März 2015, 10:00–13:00, Poster A

Rheological study of anisometric pigment particle suspensions — •Yong Geng, Alexey Eremin, and Ralf Stannarius — Otto-von-Guericke-Universität Magdeburg, FNW/IEP/ANP, Postfach 4120, 39016 Magdeburg, Germany

Rheological properties of colloidal suspensions formed by nanometer size rod-shaped pigment particles dispersed in a non-polar solvent are studied. Experiments have shown that these suspensions possess unusual properties such as liquid crystalline behaviour at high dispersant concentration, field-induced phase separation at low and intermediate concentrations, switching in electric fields, and a reversible response to the adsorbing light affecting current transients in sandwich cells.1,2 By doping with small amounts of ferrofluid these pigment dispersions can form a basis for magneto-responsive materials. A strong magneto-optical effect has been confirmed. In our studies, we demonstrate a strong shear-induced birefringence and shear thinning behaviour in pure dispersions. We also discuss the effects of magnetic fields on the rheological properties of the pigment/ferrofluid mixtures. This helped to get a deeper insight into the properties of these suspensions and understand the mechanisms of the structural changes under external field such as electric, magnetic and flow.

1. Eremin, Alexey, et al., Adv. Funct. Materials 21.3 (2011): 556-564. 2. Greasty, Robert J., et al., Phil. Trans. Roy. Soc. A 371.1988 (2013): 20120257.