Berlin 2015 – scientific programme

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 55: Flow-Induced Structures in Complex Fluids (with DRG, Deutsche Rheologische Gesellschaft, and DY)

CPP 55.6: Talk

Wednesday, March 18, 2015, 16:30–16:45, C 264

Rheological properties of temporarily cross-linked microcapsules — •Sarah Demand and Heinz Rehage — Chair of Physical Chemistry II, TU Dortmund, 44227 Dortmund, Germany

Microcapsules have a broad spectrum of different applications and can be used as simple model systems for understanding the mechanical properties and controlled release processes of biological cells, e. g. erythrocytes. Capsules consist of a tiny fluid droplet which is surrounded by an ultra-thin, flexible membrane. Temporary networks, which simply emerge from self-organization processes of surfactants, are of special interest. These coherent films exhibit striking viscoelastic properties which are influenced by dynamic fluctuations and the average life-time of cross-linking points. A typical emulsifying compound, showing this special ambivalent behavior, is the polysaccharide surfactant Span 65. In order to measure the kinetics of crosslinking and the stability of Span 65-films, we performed different types of rheological investigations. The shear and dilatational behavior of microcapsules was obtained from deformation studies in external fields. Capsule deformations in centrifugal fields were studied in a spinning-drop tensiometer. The deformation and orientation behavior in simple shear flow was investigated by means of an optical rheoscope. The results of all the studies showed a high ability of temporarily cross-linked surfactant films to stabilize emulsion droplets. Due to their processes of self-organization, this provides new and interesting perspectives for simple and effective micro- and nano-capsule technologies.