Berlin 2015 – scientific programme

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 8: Colloids and Complex Liquids II (joint session CPP, BP, DY)

CPP 8.1: Talk

Monday, March 16, 2015, 15:00–15:15, C 130

TIRM at liquid/liquid interfaces — •Kilian Dietrich — University of Stuttgart, Germany

Total Internal Reflection Microscopy (TIRM) is a well-established method for the direct measurement of interaction potentials between a spherical colloidal particle and a solid wall. It is based on the tracking of the particle's vertical motion from which interaction forces with the interface can be inferred with a resolution down to 10fN. In contrast to previous measurements, which were performed at solid/liquid interfaces, here we demonstrate that TIRM can be applied also to liquid/liquid interfaces. These are of special interest not only due to their frequent appearance but they also exhibit an exceptional smoothness. In our study, we present a novel inverted TIRM apparatus which is capable to measure the motion of a colloidal probe particle in water close to an oil-water interface. First measurements indicate the counterplay of electrostatic interactions and van-der-Waals forces for interfaces treated with different ionic and non-ionic surfactants. In each case surface charge densities of particle and interface could be determined. The detailed knowledge of interactions can provide valuable information for the stability of emulsions and dispersions.