Heidelberg 2015 – wissenschaftliches Programm

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MS: Fachverband Massenspektrometrie

MS 14: Accelerator Mass Spectrometry and Applications 4

MS 14.7: Vortrag

Freitag, 27. März 2015, 12:45–13:00, PH/HS2

AMS of actinides in ground- and seawater: a new procedure for simultaneous analysis of U, Np, Pu, Am and Cm isotopes below ppq levels — •Francesca Quinto¹, Markus Lagos¹, Markus Plaschke¹, Thorsten Schäfer¹, Peter Steier², and Horst Geckeis¹ — ¹Institut für Nukleare Entsorgung, KIT, Eggenstein-Leopoldshafen, Germany — ²VERA Laboratory, University of Vienna, Vienna, Austria

U-236, Np-237, Pu isotopes and Am-243 were determined in ground- and seawater samples at levels below ppq with a maximum sample size of 0.250 l. Such high sensitivity measurement was possible by using accelerator mass spectrometry (AMS) with an improved gas stripping and an additional high resolving magnet. The use of non-isotopic tracers was investigated in order to allow the determination of those nuclides, namely Np-237 and Am-243, for which isotopic tracers for mass spectrometry are rarely available. The actinides were concentrated from the sample matrix via iron hydroxide co-precipitation and measured sequentially without previous chemical separation from each other. The analytical method was validated with the analysis of IAEA 443 seawater Reference Material and applied to background samples from the Colloid Formation and Migration project at the Grimsel Test Site and to sea- and freshwater samples affected solely by global fallout. The sensitivity of the presented analytical method provides the capability to study the long-term release of actinide tracers in field experiments as well as the transport of actinides in a variety of environmental systems.