Regensburg 2016 – wissenschaftliches Programm

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 2: Symposium SYHP: Fundamentals of Hybrid and Perovskite Photovoltaics (CPP/DS/DF/HL, organized by CPP)

CPP 2.4: Hauptvortrag

Montag, 7. März 2016, 11:15–11:45, H1

Photovoltage losses in perovskite solar cells — •Kristofer Tvingsted — Experimental Physics VI, Julius Maximilians Universität, Würzburg, Germany

Perovskite PVs have reached significant power conversion efficiency in a very short time period. Apart from providing a rather high photocurrent, they also retain a comparatively high open circuit voltage (VOC). The VOC of most solar cells is however far from its potential upper limit due to charge carrier recombination of various types, whose origin must be accurately determined. Herein, I summarize what we have learned about these photovoltage losses by studying the radiative part of recombination in Perovskites. By accurate determination of the present solar cells radiative efficiency, that is their ability to emit light, we conclude how far the solar cells are from their own thermodynamic upper limit and further, how they relate to a reference OPV cell. We evaluate the carrier density dependence of the radiative efficiency and associate it to the ideality factor, which in itself represents a uniform figure of merit for the dominant type of recombination. We show that, as the perovskite steady state photoluminescence is strong at open circuit conditions, but substantially quenched only at short circuit, they perform in this respect just as an ideal solar cell should do, and also very different from most OPVs or DSSC cells studied so far. Substantially improving the radiative efficiency to increase the open circuit voltage is a promising route to put these new photovoltaic converters in efficiency parity with the best inorganic counterparts.