Regensburg 2016 – wissenschaftliches Programm

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 27: Poster: Soft Matter Dynamics / Glasses

CPP 27.2: Poster

Dienstag, 8. März 2016, 18:15–21:00, Poster B2

Molecular Mobility and Gas Transport Properties of PIM-1 and Nano composites based on PIM-1 and PhenethylPOSS — Nora Konnertz, Yi Ding, Martin Böhning, and •Andreas Schönhals — Bundesanstalt für Materialforschung und -prüfung (BAM), Unter den Eichen 87, 12205 Berlin

Polymers with intrinsic microporosity are of highly interest in the field of gas separation membranes. Especially the first synthesized PIM-1 shows extraordinary permeabilities and selectivities. Unfortunately, PIM-1 tends to physical aging and loses its good properties. Physical aging is related to the molecular mobility of PIM-1 which was here investigated by broadband dielectric spectroscopy (BDS). Besides the studies on pure PIM-1 a polyhedral oligomeric silsesquioxane with phenethyl substituents (PhenethylPOSS) was used as nanofiller (0 - 40 wt-%) in the PIM-1 matrix to improve the gas transport properties and prevent physical aging. The molecular mobility of the solution casted nano composite films was analyzed by BDS as well. Furthermore, gas transport properties were determined with the time lag method (0 - 20 bar) in a temperature range of 35°C to 65°C with N2, O2, CH4 and CO2.