Regensburg 2016 – wissenschaftliches Programm

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 6: Colloids and Complex Fluids II (joint session BP/CPP/DY, organized by CPP)

CPP 6.1: Hauptvortrag

Montag, 7. März 2016, 09:30–10:00, H51

Dynamics of thermosensitive core-shell dumbbells as analyzed by rheo-SANS — •Matthias Ballauff — Helmholtz-Zentrum Berlin

We present a study of the dynamics of dumbbell-shaped colloids. The thermosensitive dumbbell-shaped microgels consist of a solid polystyrene core and a thermosensitive shell of cross-linked poly(N-isopropylacrylamide). These colloidal particles are nearly monodisperse as shown by cryogenic transmission electron microscopy. The aspect ratio L* defined by the ratio of the center distance L to the diameter D can be varied between 0.24 and 0.3. The effective volume fraction can be varied by temperature and high volume fractions can be achieved easily because of the thermosensitive shell [1]. We observe the formation of a plastic crystal in these suspensions about of volume fraction of 0.5 as predicted by theory. This is shown from rheological evidence and by the Bragg-reflections of the crystals. For higher volume fraction a glassy state is formed. Moreover, oscillatory experiments in the linear viscoelastic regime and flow curves up to volume fractions of nearly 0.7 have been obtained. Recent studies based on a combination of rheoSANS experiments and BD-simulations revealed the formation of a novel, partially oriented phase formed by dumbbells under shear. All data demonstrate that these particles present a novel model system for the study of the rheology of slightly anisotropic particles.

[1] F. Chu, et al., Macromol. Rapid Comm. 33 (2012) 1042.