Regensburg 2016 – scientific programme
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DS: Fachverband Dünne Schichten
DS 53: Postersession DS/HL
DS 53.5: Poster
Thursday, March 10, 2016, 16:00–19:00, Poster A
Spectroscopic Ellipsometry and MOKE as a Probe for Structural Properties of Spinel Oxide Thin Films — •Vitaly Zviagin1, Peter Richter2, Yogesh Kumar1, Israel Lorite1, Michael Lorenz1, Daniel Spemann1, Jan Meijer1, Dietrich R.T. Zahn2, Georgeta Salvan2, Pablo Esquinazi1, Marius Grundmann1, and Rüdiger Schmidt-Grund1 — 1Universtät Leipzig, Institut für Experimentelle Physik II, Linnéstr. 5, Germany — 2Technische Universtät Chemnitz, Semiconductor Physics, Reichenheiner Str. 70, Germany
Normal, disordered, and inverse spinel oxide ferrite and cobaltite thin films were grown at different temperatures on MgO (100), MgAl2O4 (100), and SrTiO3 (100) substrates by pulsed laser deposition. Assigned electronic transitions visible in diagonal and off-diagonal elements of the dielectric tensor show a clear dependence on growth temperature corresponding to the crystal quality of the films. Silicon irradiation of ZnFe2O4 films caused inversion of normal spinel structure as well as lattice distortion with further treatment, clearly visible in the dielectric function. The ZnxFe3−xO4 composition was found to contain defects such as presence of Fe2+ ions. Magneto-optical Kerr effect spectroscopy was employed to investigate magneto-optically active transitions, and in combination with spectroscopic ellipsometry we obtained detailed information of site occupancy related to crystal inversion and disorder. We relate optical properties to magnetic properties to show a direct correlation between site occupancy of tetrahedral sites by Fe3+ ions to saturation and remanence magnetization.