Regensburg 2016 – wissenschaftliches Programm
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TT: Fachverband Tiefe Temperaturen
TT 59: Low-Dimensional Systems: Poster Session
TT 59.17: Poster
Mittwoch, 9. März 2016, 15:00–18:30, Poster D
Electronic reconstruction at the interface between the Mott insulator LaVO3 and the band insulator SrTiO3 — •Martin Stübinger, Judith Gabel, Philipp Gagel, Michael Sing, and Ralph Claessen — Universität Würzburg, Physikalisches Institut and Röntgen Center for Complex Material Systems (RCCM), 97074 Würzburg, Germany
Akin to the well known oxide heterostructure LaAlO3/SrTiO3 (LAO/STO) the formation of a conducting interface is found between the strongly correlated, polar Mott insulator LaV3+O3 (LVO) and the non-polar band insulator STO. Since LaV3+O3 tends to overoxidize to the thermodynamically more favourable LaV5+O4 phase when exposed to air, a suitable passivation is required. Therefore, we have employed pulsed laser deposition thin film growth of LVO films with a crystalline LAO capping layer. In situ photoemission measurements of samples before and after being exposed to air show that the V oxidation state can indeed be stabilized by the LAO capping layer. By transport measurements, we identify an insulator-to-metal transition at a combined LAO/LVO overlayer thickness of 4 to 5 unit cells. With LVO being a Mott insulator, passivation by the LAO capping opens the opportunity to study a band-filling controlled Mott insulator to metal transition induced by a purely electrostatic mechanism without interfering overoxidation of the LVO film.