Dresden 2017 – wissenschaftliches Programm

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 70: Organic Electronics and Photovoltaics V: OPV (joint session CPP/DS/HL, organized by CPP)

CPP 70.5: Hauptvortrag

Freitag, 24. März 2017, 11:15–11:45, ZEU 255

Charge transfer states for organic opto-electronics — •Koen Vandewal — Dresden Integrated Center for Applied Physics and Photonic Materials (IAPP) and Institute for Applied Physics, Technische Universität Dresden, George-Bähr-Strasse 1, 01062, Dresden, Germany

Intermolecular charge transfer (CT) states at the interface between electron-donating and electron-accepting (A) materials in organic thin films are characterized by absorption and emission bands within the optical gap of the interfacing materials. Depending on the used donor and acceptor materials, CT states can be very emissive, or generate free carriers at high yield. The former can result in rather efficient organic light emitting diodes, via thermally activated delayed fluorescence, while the latter property is exploited in organic photovoltaic devices and photodetectors. In this contribution, we will discuss the fundamental properties of CT states and link them to organic opto-electronic device performance. Furthermore, we introduce a new device concept, using an optical cavity resonance effect to boost CT absorption at photon energies below the optical gap of both donor and acceptor, enabling narrow-band, near infrared (NIR) photo-detection.