Mainz 2017 – wissenschaftliches Programm
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MO: Fachverband Molekülphysik
MO 9: Posters 1: Dichroism, VUV and Xray, Clusters, and Cold Molecules
MO 9.16: Poster
Dienstag, 7. März 2017, 17:00–19:00, P OG1
BerlinTrap: A novel cryogenic 22-pole tandem mass spectrometer — •Pablo Nieto, Alan Günther, David Müller, Alex Sheldrick, and Otto Dopfer — Institut für Optik und Atomare Physik, Technische Universität Berlin, Hardenbergstr. 36, D-10623 Berlin, Germany
We present the design and first applications of a new tandem mass spectrometer (BerlinTrap) combining an electrospray ion source, a quadrupole mass spectrometer, a cryogenic 22-pole ion trap (4-300 K), and an orthogonal reflectron time-of-flight mass spectrometer [1]. The trapped ions are cooled by helium buffer gas cooling. The formation and solvation shell structure of weakly-bound HenH3O+ complexes and the electronic photodissociation spectrum of the protonated amino acid tyrosine are used to calibrate the setup for cooling, tagging, and spectroscopic capabilities. A vibrational temperature below 20 K is inferred for protonated tyrosine. The electronic spectrum of isolated protonated lumichrome, the smallest protonated flavin, is recorded in the visible range and assigned to the most stable N5 isomer by comparison with quantum chemical calculations. These results demonstrate the suitability of the BerlinTrap apparatus for spectroscopy and reactivity studies of small and large (bio-)molecular ions and their clusters.
[1] A. Günther, P. Nieto, D. Müller, A. Sheldrick, D. Gerlich, and O. Dopfer, J. Mol. Spectrosc., in press, DOI:10.1016/j.jms.2016.08.017